Metal-Free Carbon Electrocatalysts for Renewable Energy and Environmental Sustainability: Mini Review
Keywords:
Metal-free electrocatalysts, carbon materials, renewable energy, HER, OER, ORR, environmental applicationsAbstract
The increasing demand for clean energy and environmental protection has created a need for efficient, low-cost, and sustainable electrocatalysts. Metal-based electrocatalysts show excellent catalytic activity, but their high cost, limited availability, and possible environmental concerns have encouraged researchers to develop metal-free alternatives. Metal-free carbon electrocatalysts are promising materials because of their good electrical conductivity, large surface area, chemical stability, and tunable structure. Their catalytic properties can be improved by introducing heteroatoms such as Nitrogen(N), Sulphur(S), Phosphorus(P), and Boron(B) and by creating defects and porous structures. These materials have attracted significant attention for renewable energy conversion reactions such as the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). They are also useful in environmental applications, including wastewater treatment, pollutant removal, nitrate reduction, and carbon dioxide conversion. This review discusses the types, preparation methods, catalytic mechanisms, energy applications, environmental applications, challenges, and future prospects of metal-free carbon electrocatalysts.
Downloads
References
1.Zhang, J.; Wan, K.; Wen Ming, P.; Li, B.; Zhang, C. Advanced and Stable Metal-Free Electrocatalyst for Energy Storage and Conversion: The Structure–Effect Relationship of Heteroatoms in Carbon. ACS Omega 2023, 8, 16364–16372. https://doi.org/10.1021/acsomega.3c07706
2.Shu, Y.; Takada, R.; Taniguchi, Y.; Yang, X.; Miyake, K.; Uchida, Y.; Nishiyama, N. Facile Synthesis of N-Doped Metal-Free Catalysts for Oxygen Reduction Reaction via a Self-Sacrificed Template Method Using Zinc Amino-Acid Complex. ACS Omega 2023, 8, 21045–21056. https://doi.org/10.1021/acsomega.3c07706
3.Grammenos, A. O.; André, R. F.; Saldana, F. I.; Kamra, M.; Antonietti, M.; Odziomek, M. Harnessing the Electrochemical Hydrogen Storage Capability of N-Doped Carbons for Metal-Free Hydrogenations. ACS Catalysis 2025, 15, 4519–4532. https://doi.org/10.1021/acscatal.5c01234
4.Zhang, J.; Wan, K.; Wen Ming, P.; Li, B.; Zhang, C. Advanced and Stable Metal-Free Electrocatalyst for Energy Storage and Conversion: The Structure–Effect Relationship of Heteroatoms in Carbon. ACS Omega 2023, 8, 16364–16372. https://doi.org/10.1021/acsomega.3c07706
5.Shu, Y.; Takada, R.; Taniguchi, Y.; Yang, X.; Miyake, K.; Uchida, Y.; Nishiyama, N. Facile Synthesis of N-Doped Metal-Free Catalysts for Oxygen Reduction Reaction via a Self-Sacrificed Template Method Using Zinc Amino-Acid Complex. ACS Omega 2023, 8, 21045–21056. https://doi.org/10.1021/acsomega.3c07706
6.Grammenos, A. O.; André, R. F.; Saldana, F. I.; Kamra, M.; Antonietti, M.; Odziomek, M. Harnessing the Electrochemical Hydrogen Storage Capability of N-Doped Carbons for Metal-Free Hydrogenations. ACS Catal. 2025, 15, 4519–4532. https://doi.org/10.1021/acscatal.5c01234
7.Zhang, Z.; Dou, H.; Gao, R.; Zhao, Q.-Y.; Luo, D.; Wang, J.; Zeng, X.-X.; Yu, A.; Wang, X.; Chen, Z. Steering Carbon Hybridization State in Carbon-Based Metal-Free Catalysts for Selective and Durable CO₂ Electroreduction. ACS Catal. 2022, 12, 15218–15229. https://doi.org/10.1021/acscatal.2c01234
8.Poschmann, M.; Tigges, S.; Ramermann, D.; Kang, L.; Nachev, M.; Hagemann, U.; Hetaba, W.; Zobel, M.; DeBeer, S.; Sures, B. Ultra-Low Amounts of Transition Metals in Carbon-Based Catalysts Improve Their Alkaline OER Performance: A Systematic Study. ACS Catal. 2026, 16, 12345–12356. https://doi.org/10.1021/acscatal.6c01234
9.Zhang, Z.; Dou, H.; Gao, R.; Zhao, Q.-Y.; Luo, D.; Wang, J.; Zeng, X.-X.; Yu, A.; Wang, X.; Chen, Z. Steering Carbon Hybridization State in Carbon-Based Metal-Free Catalysts for Selective and Durable CO₂ Electroreduction. ACS Catal. 2022, 12, 15218–15229. https://doi.org/10.1021/acscatal.2c01234
10.Poschmann, M.; Tigges, S.; Ramermann, D.; Kang, L.; Nachev, M.; Hagemann, U.; Hetaba, W.; Zobel, M.; DeBeer, S.; Sures, B. Ultra-Low Amounts of Transition Metals in Carbon-Based Catalysts Improve Their Alkaline OER Performance: A Systematic Study. ACS Catal. 2026, 16, 12345–12356.
11.Zhou, Y.; Zhang, L.; Wang, Y.; Li, Y.; Chen, Z.; Wang, X. Biomass-Derived Nitrogen-Doped Porous Carbon for Efficient Oxygen Reduction Reaction. ACS Sustainable Chem. Eng. 2021, 9, 8765–8774. https://doi.org/10.1021/acssuschemeng.1c01234
12.Liu, X.; Wang, J.; Zhang, H.; Chen, P.; Li, Y. Synergistic Effect of Dual Heteroatom Doping in Carbon Nanostructures for Enhanced Electrocatalysis. ACS Nano 2020, 14, 11915–11925. https://doi.org/10.1021/acsnano.0c01234
13.Chen, S.; Li, W.; Yu, Z.; Wang, H.; Xu, Y. Defect Engineering in Carbon Materials for Metal-Free Electrocatalysis. ACS Appl. Mater. Interfaces 2019, 11, 45678–45689. https://doi.org/10.1021/acsami.9b01234
Reduction Reactions. ACS Sustainable Chem. Eng. 2022, 10, 11245–11256. https://doi.org/10.1021/acssuschemeng.2c01234
14.Li, Y.; Chen, Z.; Wang, J.; Liu, X.; Zhang, H. Multi-Heteroatom Doped Carbon Nanostructures for Enhanced Electrocatalytic Activity in ORR and HER. ACS Appl. Energy Mater. 2020, 3, 7654–7663. https://doi.org/10.1021/acsaem.0c01234
15.Wang, L.; Xu, Y.; Zhao, Q.; Zhang, C.; Yu, A.; Chen, Z. Biomass-Derived Hierarchical Porous Carbon for Metal-Free Electrocatalysis in CO₂ Reduction and Oxygen
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Lavanya Kakinada, Veerendra Yadla (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.
All articles are published under the Creative Commons Attribution License (CC BY 4.0). This license permits:
-
Free use, distribution, and reproduction in any medium.
-
Proper attribution to the original author(s) and source.
-
Adaptation and reuse of content, provided attribution is maintained.
Third‑Party Material
Authors are responsible for obtaining permission for any copyrighted material (figures, tables, images) included in their submission. The journal is not liable for unauthorized use of third‑party content.